## Relaxation and Creep

### Quick Start

Relaxation (reduction of stress under constant strain) and Creep (increase of strain under constant stress) are often seen as complementary. Yet the common equations for viscoelasticity work only for one or the other. Here we use an equation that can realistically show both relaxation and creep for a material, giving you a better idea of what you might see.

### Relaxation & Creep

_{0}Initial Strain %

_{0}Initial Stress (M)Pa

_{max}s

_{stop}s

_{hold}s

_{1}(M)Pa

_{11}

_{2}(M)Pa

A spring and dashpot in series give you a Maxwell fluid which can simulate Relaxation, but not Creep. A spring and dashpot in parallel give you a Kelvin-Voigt solid which can simulate Creep but not Relaxation

Here we use a "modified standard solid" model developed by Evagelia Kontou and others^{1} which has a spring and dashpot in series plus a spring and (the same) dashpot in parallel. The key is that the parallel spring is a "strain hardening" one, with no strength at zero strain, and we use a non-linear "Eyring" dashpot.

We need 5 parameters for this (rather than the two each for Maxwell and Kelvin-Voigt). So it's important to get a feel for what each one means

- E
_{1}. This is the hardening spring made from two components which I've called E_{1}& E_{11}, though in the literature these are called η_{1}& η_{2}. If E_{11}=0 then we have a simple spring. - E
_{2}. This is the Maxwell spring. - A & b. These make up the non-linear dashpot. A is the response rate or frequency, and b controls the non-linearity. When b is very small then we have a simple dashpot.

The original papers are "polymer" papers so the key values are in terms of MPa. For soft-matter rheology it makes sense to use Pa. You can switch between the two sets of units.

### Recovery

One of the distinctive features of these experiments is that if the strain or stress is suddenly removed, the system starts to recover. If the strain or stress is then re-applied after a time, the original behaviour re-starts. One such cycle can be performed with strain or stress being removed at t_{stop} and resumed after after a delay of t_{hold}.

### The Equations

The strain-hardening spring, using the η notation is, for strain ε:

E_{1=η1ε-η2}

The non-linear dashpot at stress σ is given by:

δε/δt = A.sinh[b(σ-εE_{1})]

For a constant strain ε the Relaxation curve is given by:

δσ/δt = -A.E_{2}sinh[b(σ-εE_{1})]

For constant stress σ the Creep curve is given by:

δε/δt = A.E_{2}sinh[b(σ-εE_{1}')]/[E_{2}+E_{1}(1+η_{2})] where E_{1}' = η_{1}ε^{1-η2}

^{1}I have used two papers to provide equations I can use and a default example. Antonios Zacharatos, Evagelia Kontou, *Nonlinear viscoelastic modeling of soft polymers*, J. APPL. POLYM. SCI. 2015, DOI: 10.1002/APP.42141, Rui Miranda Guedes1, Anurag Singh and Viviana Pinto, *Viscoelastic Modelling of Creep and Stress Relaxation Behaviour in PLA-PCL Fibres*, Fibers and Polymers 2017, 18, 2443-2453